Paul Giem has just published another article in the journal Origins. Paul has been looking at the possible reasons why low level C-14 is found in fossil carbon. As you have seen on this web site, the evolutionary expectation is that there should be no C-14 present in the fossil samples. You will find the material presented in this web site as a good background for his discussion of the alternate explanations as to why C-14 is present in fossil materials.
His article (I am quoting from portions of his abstract), Carbon-14, Content of Fossil Carbon reviews the theoretical basis for expecting the presence of carbon-14 in Pliocene to Cambrian carbon from certain creationist viewpoints, and for expecting its absence from a viewpoint proposing a long age of life on Earth.
He makes several conclusions in his article:
- There is measurable carbon-14 in material that should be "dead" according to standard evolutionary theory.
- Machine error can be eliminated as an explanation for this carbon-14 on experimental grounds.
- Nuclear synthesis of this carbon-14 in situ can be eliminated on theoretical grounds.
- Contamination of fossil material in situ is unlikely but theoretically possible, and is a testable hypothesis.
- Contamination during sample preparation is a significant problem but theoretically soluble.
- Residual activity is most likely indicated by the present data, and if correct, would eliminate an age greater than approximately 100,000 years for life on Earth.
- Additional experimental evidence cannot eliminate either a short or a long age of life on Earth, but can provide evidence tending to discriminate between the two.
The Geoscience Research Institutewhich publishes Origins, has now made their journal available to the web. Paul's article, Carbon-14 Content of Fossil Carbon is on the web. You can view the paper for free (no user fees).
NOTE: The following chart is taken from the paper disscussed above. The chart in the paper does not show the age of the fossil material, only pmc ratios are given. To make the data easier to understand, I have added the ages of the fossils to the chart.
Radiocarbon Measurements on "Dead" Carbon |
| 0 Apparent C-14 Age + 0 |
0 C14/C ratio (pmc) ++ 0 |
Material |
Reference |
| 39,700 years +- ? |
0.71 +- ? * |
Marble |
Aerts-Bijma et al. 1997 |
| 41,000 +- 1400 years |
0.61 +- 0.12 |
Foraminifera |
Arnold et al. 1987 |
| 41,000 +- 500 years |
0.60 +- 0.04 |
Commercial graphite |
Schmidt et al. 1987 |
| 42,000 +- 600 years |
0.52 +- 0.04 |
Whale bone |
Jull et al. 1986 |
| 42,000 +- 1000 years |
0.51 +- 0.08 |
Marble |
Gulliksen & Thomsen 1992 |
| 43,000 +- ? years |
0.5 +- ? |
Dolomite (dirty) |
Middleton et al. 1989 |
| 43,000 +- 1000 years |
0.5 +- 0.1 |
Wood, 60 Ka |
Gillespie & Hedges 1984 |
| 44,000 +- 600 years |
0.42 +- 0.03 |
Anthracite |
Grootes et al. 1986 |
| 44,300 +- 1500 years |
0.401 +- 0.084 |
Foraminifera (untreated) |
Schleicher et al. 1998 |
| 44,800 +- 890 years |
0.383 +- 0.045 |
Wood (charred) |
Snelling 1997 |
| 45,200 +- 710 years |
0.358 +- 0.033 |
Anthracite |
Beukins et al. 1992 |
| 45,600 +- 830 years |
0.342 +- 0.037 |
Wood |
Beukins et al. 1992 |
| 46,000 +- 2300 years |
0.34 +- 0.11 |
Recycled graphite |
Arnold et al. 1987 |
| 46,000 +- 1000 years |
0.32 +- 0.06 |
Foraminifera |
Gulliksen & Thomsen 1992 |
| 47,000 +- ? years |
0.3 +- ? |
Coke |
Terrasi et al. 1990 |
| 47,000 +- ? years |
0.3 +- ? |
Coal |
Schleicher et al. 1998 |
| 48,000 +- 600 years |
0.26 +- 0.02 |
Marble |
Schmidt et al. 1987 |
| 48,700 +- 1900 years |
0.2334 +- 0.061 |
Carbon powder |
McNichol et al. 1995 |
| 49,500 +- 660 years |
0.211 +- 0.018 |
Fossil wood |
Beukins et al. 1990 |
| 50,000 +- 700 years |
0.21 +- 0.02 |
Marble |
Schmidt et al. 1987 |
| 50,000 +- 2000 years |
0.21 +- 0.06 |
CO2 (source?) |
Grootes et al. 1986 |
| 45,000 - 50,000 years |
0.20 - 0.35 * (range) |
Anthracite |
Aerts-Bijma et al. 1997 |
| 50,000 +- 3000 years |
0.2 +- 0.1 * |
Calcite |
Donahue et al. 1997 |
| 50,000 +- 2100 years |
0.198 +- 0.060 |
Carbon powder |
McNichol et al. 1995 |
| 50,000 +- 2000 years |
0.198 +- 0.060 |
Marble |
Van der Borg et al. 1997 |
| 51,000 +- 1000 years |
0.18 +- 0.03 |
Whale bone |
Gulliksen & Thomsen 1992 |
| 51,000 +- 1000 years |
0.18 +- 0.03 |
Calcite |
Gulliksen & Thomsen 1992 |
| 51,000 +- 400 years |
0.18 +- 0.01 ** |
Anthracite |
Nelson et al. 1986 |
| 51,000 +- ? years |
0.18 +- ? |
Recycled graphite |
Van der Borg et al. 1997 |
| 51,000 +- 1000 years |
0.17 +- 0.03 |
Natural gas |
Guilliksen & Thomsen 1992 |
| 51,400 +- 400 years |
0.166 +- 0.008 |
Foraminifera (treated) |
Schleicher et al. 1998 |
| 51,600 +- ? years |
0.162 +- ? |
Wood |
Kirner et al. 1997 |
| 52,000 +- 1000 years |
0.16 +- 0.03 |
Wood |
Gulliksen & Thomsen 1992 |
| 52,000 +- ? years |
0.154 +- ? ** |
Anthracite coal |
Schmidt et al. 1997 |
| 52,100 +- 1200 years |
0.152 +- 0.025 |
Wood |
Beukins 1990 |
| 52,700 +- 1200 years |
0.142 +- 0.023 |
Anthracite |
Vogel et al. 1987 |
| 52,700 +- 1400 years |
0.142 +- 0.028 |
CaC2 from coal |
Gurfinkel 1987 |
| 53,000 +- 1000 years |
0.14 +- 0.02 |
Marble |
Schleicher et al. 1998 |
| 53,400 +- 500 years |
0.130 +- 0.009 |
Graphite |
Gurfinkel 1987 |
| 53,500 +- 2900 years |
0.128 +- 0.056 |
Graphite ("unknown provenance") |
Vogel et al. 1987 |
| 53,700 +- 3100 years |
0.125 +- 0.060 |
Calcite |
Vogel et al. 1987 |
| 54,600 +- 3300 years |
0.112 +- 0.057 |
Bituminous coal |
Kitagawa et al. 1993 |
| 55,000 +- 800 years |
0.1 +- 0.01 |
Graphite (NBS) |
Donahue et al. 1990 |
| 55,000 +- 3000 years |
0.1 +- 0.05 |
Petroleum, cracked |
Gillespie & Hedges 1984 |
| 56,000 +- 700 years |
0.098 +- 0.009* |
Marble |
Schleicher et al. 1998 |
| 56,000 +- 500 years |
0.092 +- 0.006 |
Wood |
Kirner et al. 1995 |
| 51,000 - 56,000 years |
0.09 - 0.18 * (range) |
Graphite powder |
Aerts-Bijma et al. 1997 |
| 53,000 - 56,000 years |
0.09 - 0.13 * (range) |
Fossil CO2 gas |
Aerts-Bijma et al. 1997 |
| 56,000 +- 1400 years |
0.089 +- 0.017 |
Graphite |
Arnold et al. 1987 |
| 57,000 +- 1700 years |
0.081 +- 0.019 |
Anthracite |
Beukins 1992 |
| 57,000 +- ? years |
0.08 +- ? |
Natural Graphite |
Donahue et al. 1984 |
| 58,000 +- 500 years |
0.077 +- 0.005 |
Natural Gas |
Beukins 1992 |
| 58,000 +- 900 years |
0.076 +- 0.009 |
Marble |
Beukins 1992 |
| 58,000 +- ? years |
0.07 +- ? |
Graphite |
Kretschmer et al. 1998 |
| 59,000 +- 1000 years |
0.068 +- 0.009 |
Graphite (fresh surface) |
Schmidt et al. 1987 |
| 55,000 - 60,000 years |
0.06 +- 0.11 (range) |
200 Ma old graphite |
Nakai et al. 1984 |
| 37,600 - 59,600 years |
0.060 +- 0.932 (range) |
Marble |
McNichol et al. 1995 |
| 60,000 +- ? years |
0.056 +- ? |
Wood (selected data) |
Kirner et al. 1997 |
| 61,000 +- 1000 years |
0.05 +- 0.01 |
Carbon |
Wild et al. 1998 |
| 61,000 +- ? years |
0.05 +- ? |
Carbon-12 (mass sp.) |
Schmidt et al. 1987 |
| 62,000 - 73,000 (m 60,000) years |
0.045 - 0.012 (m 0.06) |
Graphite |
Grootes et al. 1986 |
| 62,000 +- ? years |
0.044 +- ? |
Coal Tar |
Farwell et al. 1984 |
| 63,000 +- ? years |
0.04 +- ? * |
Graphite rod |
Aerts-Bijma et al. 1997 |
| 63,000 +- 2000 years |
0.04 +- 0.01 |
Finnish graphite |
Bonani et al. 1986 |
| 63,000 +- 4000 years |
0.04 +- 0.02 |
Graphite |
Van der Borg et al. 1997 |
| 64,000 +- 1000 years |
0.036 +- 0.005 |
Graphite (air) |
Schmidt et al. 1987 |
| 64,000 +- 2700 years |
0.033 +- 0.013 |
Graphite |
Kirner et al. 1995 |
| 65,000 +- 3300 years |
0.03 +- 0.015 |
Carbon powder |
Schleicher et al 1998 |
| 65,000 +- 2000 years |
0.030 +- 0.007 |
Graphite (air redone) |
Schmidt et al. 1987 |
| 65,000 +- 1500 years |
0.029 +- 0.006 |
Graphite (argon redone) |
Schmidt et al. 1987 |
| 65,000 +- 2400 years |
0.029 +- 0.010 |
Graphite (fresh surface) |
Schmidt et al. 1987 |
| 68,000 +- ? years |
0.02 +- ? |
Carbon powder |
Pearson et al. 1998 |
| 69,000 +- 1500 years |
0.019 +- 0.004 |
Graphite (argon) |
Schmidt et al. 1987 |
| 71,000 +- 4300 years |
0.014 +- 0.010 |
CaC2 (technical grade |
Beukins 1993 |
| 74,000 +- ? years |
0.01 +- ? ** |
Dolomite (clean) |
Middleton et al. 1989 |
(infinity) 155,000 +- 5,000 years |
0. +- 0.0000004 |
Methane |
Beukins 1993 |
+ The Apparent C-14 Age is calculated from the pmc numbers by assuming the uniformitarian model. (The standard 5568 year half-life for C-14 is assumed.) The equation used in this chart is: Time = -(log(pmc/100)/log (2))*5568 The Apparent C-14 Age is added for those who might find it hard to understand the pmc numbers. ++ pmc = percent modern carbon. [= C14/C ratio expressed as a percentage of that found in the "modern" (1850) biosphere] * Estimated from graph. ** Lowest value of multiple dates. |
This Table has been modified from its original form from Table I in Paul Giem's paper; Carbon-14 Content of Fossil Carbon, Origins No. 51:6-30, 2001 |
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